POTASSIUM CYANATE

PRODUCT IDENTIFICATION

CAS NO. 590-28-3

POTASSIUM CYANATE

EINECS NO. 209-676-3
FORMULA KOCN
MOL WT. 81.11

H.S. CODE

2838.00
TOXICITY  
SYNONYMS Aero cyanate; Cyanic acid, potassium salt;
Kaliumcyanat (German); Cianato de potasio (Spanish); Cyanate de potassium (French);
SMILES  

CLASSIFICATION

 

PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE white crystalline powder
MELTING POINT 314 - 316 C
BOILING POINT 700 C (Decomposes)
SPECIFIC GRAVITY 2.05 -2.06
SOLUBILITY IN WATER 750 (g/l at 20 C)
pH 10
VAPOR DENSITY  

AUTOIGNITION

 

NFPA RATINGS

Health: 1; Flammability: 0; Reactivity: 0

REFRACTIVE INDEX

 

FLASH POINT  
STABILITY Stable under ordinary conditions.

GENERAL DESCRIPTION AND APPLICATIONS

Cyanic acid (the isomer of fulminic acid) is an unstable (explosive), poisonous, volatile, clear liquid with the structure of H-O-C≡N (the oxoacid formed from the pseudohalogen cyanide), which is readily converted to cyamelide and fulminic acid. There is another isomeric cyanic acid with the structure of H-N=C=O, called isocyanic acid. Cyanate group (and isocyanate group) can react with itself. Cyanuric acid (also called pyrolithic acid), white monoclinic crystal with the structure of [HOC(NCOH)2N], is the trimer of cyanic acid. The trimer of isocyanic acid is called biuret.
  • Cyanic acid: H-N=C=O or H-O-C≡N
  • Fulminic acid: (H-C=N-O) or H-C≡N-O
  • Isocyanic acid: H-N=C=O
  • Cyanuric acid: HOC(NCOH)2N
  • Biuret: (NH2)CO)2 NH

Cyanic acid hydrolyses to ammonia and carbon dioxide in water. The salts and esters of cyanic acid are cyanates. But esters of normal cyanic acid are not known. The salts and esters of isocyanic acid are isocyanates. The isocyanate group reacts with the hydroxyl functional group to form a urethane linkage. Diisocyanates (or polyisocyanates) are monomers for polyurethane production. Polyurethane is made from a variety of diisocyanates in conjunction with polyether and polyester polyols as co-reactants by addition polymerization which needs at least two -N=C=O groups. Polyurethanes are widely used in the manufacture of flexible and rigid foams, fibres, coatings, and elastomers. If isocyanate monomer is polymerized with amine group, polyurea is produced. Cyanates (or Isocyanates) are readily reacts with various form of amine (including ammonia, primary-, secondary-amines, amides and ureas) and hydroxyl functional group. They are used in the synthesis for the target molecules such as pharmaceuticals, pesticides, textile softener, lubricants and industrial disinfectants. They can convert to polycyclic compounds such as hydantoins and imidazolons. They are used as plastic additives and as heat treatment salt formulations for metals.

SALES SPECIFICATION

APPEARANCE

white crystalline powder
ASSAY 97.0% min (or 85.0% min)
POTASSIUM CYANIDE

1.0% max

TRANSPORTATION
PACKING 25kgs, 500kgs in bag
HAZARD CLASS  
UN NO.  
OTHER INFORMATION
Hazard Symbols: XN, Risk Phrases: 22, Safety Phrases: 24/25